A Novel Tetranuclear Silver Compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a Simple Synthesis Yielding Complex Crystal Structure

Authors

  • Marta Počkaj Faculty of Chemistry and Chemical Technology, University of Ljubljana Večna pot 113, SI-1000 Ljubljana, Slovenia
  • Nives Kitanovski Faculty of Chemistry and Chemical Technology, University of Ljubljana Večna pot 113, SI-1000 Ljubljana, Slovenia

DOI:

https://doi.org/10.17344/acsi.2021.6961

Keywords:

coordination chemistry, silver, bis(3, 5-dimethylpyrazol -1-yl)acetate, crystal structure, Hirshfeld surface analysis

Abstract

A novel tetranuclear silver coordination compound with the formula [Ag4(bdmpza)4]×10H2O (bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate) was synthesized by a reaction between an aqueous solution of silver nitrate and an aqueous solution prepared by bis(3,5-dimethylpyrazol-1-yl)acetic acid and potassium  hydroxide (1:1 molar ratio). The obtained compound was characterized by elemental analysis, coupled thermogravimetric–mass spectrometry analysis, vibrational IR spectroscopy, and its crystal structure was determined by single-crystal X-ray diffraction method. Furthermore, the obtained crystal structure was additionally evaluated by Hirshfeld surface analysis.

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Published

15.09.2021

Issue

Vol. 68 No. 3 (2021)

Section

Inorganic chemistry

License

Except where otherwise noted, articles in this journal are published under the Creative Commons Attribution 4.0 International License