Synthesis and reduction of 10-phthalimidocamphor oxime

Authors

  • Uroš Grošelj University of Ljubljana Faculty of Chemistry and Chemical Technology Chair of Organic Chemistry
  • Amalija Golobič University of Ljubljana Faculty of Chemistry and Chemical Technology Chair of Inorganic Chemistry
  • Jurij Svete University of Ljubljana Faculty of Chemistry and Chemical Technology Chair of Organic Chemistry
  • Sebastijan Ričko University of Ljubljana Faculty of Chemistry and Chemical Technology Chair of Organic Chemistry

DOI:

https://doi.org/10.17344/acsi.2017.3474

Keywords:

10-iodocamphor, 10-phthalimidocamphor oxime, camphor derived amines, reduction

Abstract

10-Phthalimidocamphor oxime was prepared from easily available 10-iodocamphor in two steps. Reduction of the oxime functionality resulted in the formation of two novel polycyclic isoindolinone heterocycles, the attempted preparation of the primary amine failed. The structures of novel heterocycles were unambiguously confirmed by single crystal X-ray diffraction as well as NMR techniques.

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Published

12.12.2017

Issue

Vol. 64 No. 4 (2017): Acsi

Section

Organic chemistry

License

Except where otherwise noted, articles in this journal are published under the Creative Commons Attribution 4.0 International License