A one-pot multicomponent reaction for the synthesis of oligoetherols with azacyclic rings

Authors

  • Jacek Marek Lubczak Department of Organic Chemistry, Faculty of Chemistry, University of Technology
  • Renata Lubczak Rzeszów University of Technology, Department of Organic Chemistry, Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland
  • Iwona Zarzyka Rzeszów University of Technology, Department of Organic Chemistry, Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland

DOI:

https://doi.org/10.17344/acsi.2017.3495

Keywords:

azacyclic compounds, glycidol, alkylene carbonates, oligoetherols, one-pot multicomponent reactions, polyurethane foams

Abstract

The one-pot multicomponent synthesis of oligoetherols containing azacycles is described. They were obtained by reaction of isocyanuric, barbituric, or uric acid or melamine with glycidol and alkylene carbonates. The isolated products were characterized by physical methods and their properties were compared with the same compounds obtained in two-step protocol. The oligoetherols with 1,3,5-triazine ring obtained by both methods were then used to form polyurethane foams  and their properties were compared.

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Published

12.12.2017

Issue

Vol. 64 No. 4 (2017): Acsi

Section

Applied chemistry

License

Except where otherwise noted, articles in this journal are published under the Creative Commons Attribution 4.0 International License