Two related copper(I) π-complexes based on 2-allyl-5-(2-pyridyl)-2H-tetrazole ligand: Synthesis and structure of [Cu(2-apyt)NO3] and [Cu(2-apyt)(H2O)](BF4) compounds

Authors

  • Yurii Slyvka Ivan Franko National University of Lviv
  • Evgeny Goreshnik Department of Inorganic Chemistry and Technology, Jozef Stefan Institute, Jamova 39, SI-1000 Ljubljana
  • Nazariy Pokhodylo Department of Organic Chemistry, Ivan Franko National University, Kyryla i Mefodia Str, 6, 79005 L'viv
  • Oleksiy Pavlyuk Department of Inorganic Chemistry, Ivan Franko National University, Kyryla i Mefodia Str, 6, 79005 L'viv
  • Marian Mys’kiv Department of Inorganic Chemistry, Ivan Franko National University, Kyryla i Mefodia Str, 6, 79005 L'viv

DOI:

https://doi.org/10.17344/acsi.2016.2486

Keywords:

copper(I), tetrazole, π-complex, isomer-selective complexation, ac-technique, crystal structure.

Abstract

By means of the alternating current electrochemical technique two new [Cu(2-Apyt)NO3] (1) and [Cu(2-Apyt)(H2O)](BF4) (2) π-compounds have been obtained starting from the mixture of 1-allyl-5-(2-pyridyl)-2H-tetrazole (1-Apyt) and 2-allyl-5-(2-pyridyl)-2H-tetrazole (2-Apyt) and corresponding copper(II) salts, and structurally studied. Selective towards 2-allyl- isomer complexation results in a formation of 2-Apyt complexes.  Copper(I) ion in both 1 and 2 complexes is coordinated by allylic C=C bond, one pyridyl and one tetrazole N atoms. In both structures Cu+ center adopts distorted tetrahedral surrounding, being additionally coordinated by oxygen of NO3- in 1 and H2O moiety in 2. Coordination of bridging nitrate anion causes the dimeric [Cu(2-Apyt)NO3]2 fragment formation, while participation of H2O in metal coordination leads to infinite {[Cu(2-Apyt)(H2O)]2+}n chain construction. To analyze interactions between the particles in 1 and 2 Hirshfeld surface analysis was performed.

Downloads

Additional Files

Published

20.05.2016

Issue

Vol. 63 No. 2 (2016)

Section

Inorganic chemistry

License

Except where otherwise noted, articles in this journal are published under the Creative Commons Attribution 4.0 International License