Oxidovanadium(V) and Dioxidomolybdenum(VI) Complexes of N'-(3,5-Dichloro-2-hydroxybenzylidene)-4-fluorobenzohydrazide: Synthesis, Characterization, Crystal Structures and Catalytic Property

Authors

  • Huan-Yu Liu a School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, P.R. China b Guangdong Cosmetics Engineering and Technology Research Center, Zhongshan 528458, P.R. China
  • Yi-Shu Yin a School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, P.R. China b Guangdong Cosmetics Engineering and Technology Research Center, Zhongshan 528458, P.R. China
  • Luo-Ju Yang a School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, P.R. China b Guangdong Cosmetics Engineering and Technology Research Center, Zhongshan 528458, P.R. China
  • Xiao-Ling Zou a School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, P.R. China b Guangdong Cosmetics Engineering and Technology Research Center, Zhongshan 528458, P.R. China
  • Ya-Fang Ye a School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, P.R. China b Guangdong Cosmetics Engineering and Technology Research Center, Zhongshan 528458, P.R. China

DOI:

https://doi.org/10.17344/acsi.2019.5286

Keywords:

Hydrazone, Vanadium complex, Molybdenum complex, Crystal structure, Catalytic property

Abstract

N'-(3,5-Dichloro-2-hydroxybenzylidene)-4-fluorobenzohydrazide (H2L) was used to prepare oxidovanadium(V) complex [VOL(OEt)(MeOH)] (1) and dioxidomolybdenum(VI) complex [MoO2L(OH2)]·[MoO2L(EtOH)] (2). The complexes were characterized by IR, UV-Vis, NMR spectroscopy, and single crystal X-ray diffraction. X-ray analysis indicates that the complexes are mononuclear species with the metal atoms in octahedral coordination. The complexes were studied for catalytic oxidation property on some olefins with tert-butyl hydroperoxide as oxidant.

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Published

20.03.2020

Issue

Vol. 67 No. 1 (2020)

Section

Inorganic chemistry

License

Except where otherwise noted, articles in this journal are published under the Creative Commons Attribution 4.0 International License