Amination of aryl halides with aqueous ammonia catalyzed by green recyclable poly(4-vinylpyridine)-supported copper iodide nanoparticles catalyst

Authors

  • Jalal Albadi Behbahan Khatam Alanbia University of Technology, Behbahanm Iran
  • Jafar Abbasi Shiran
  • Azam Mansournezhad

Keywords:

Poly(4-vinylpyridine)-Supported, Copper catalysis, Nanoparticles, Amination, Aryl halide

Abstract

Efficient procedure for the amination of aryl halides with aqueous ammonia in the presence of poly(4-vinylpyridine)-supported copper iodide is reported. A wide range of aryl halides including aryl iodide and aryl bromide are converted into the corresponding aniline derivatives. The experimental procedure with poly(4-vinylpyridine)-supported copper iodide is quite straightforward  and the catalyst is recyclable up to 3 consecutive runs by simple filtration.

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Published

17.10.2014

Issue

Section

Organic chemistry