A Rarely Seen Phenolato and Azido-Bridged Polymeric Cadmium(II) Complex Derived from 2-Bromo-6-[(2-isopropylaminoethylimino)methyl]phenol

Authors

  • Guo-Ping Cheng
  • Ling-Wei Xue Pingdingshan University
  • Cai-Xia Zhang

DOI:

https://doi.org/10.17344/acsi.2016.3036

Keywords:

Self-assembly, Crystal structure, Schiff base, Cadmium complex, Thermal analysis.

Abstract

A rarely seen phenolato and azido-bridged polymeric cadmium(II) complex derived from the Schiff base ligand 2-bromo-6-[(2-isopropylaminoethylimino)methyl]phenol (HL) has been prepared and characterized by elemental analysis, IR spectroscopy, and single crystal X-ray diffraction. The Schiff base ligand coordinates to the Cd atom through the NNO donor set. The Cd atom is hexa-coordinated in an octahedral geometry. Adjacent two Cd atoms are bridged by two phenolato groups generating a dimer with Cd···Cd distance of 3.475(1) Å. The dimers are further linked via azido bridges forming 2D sheets parallel to the bc plane.

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Published

21.02.2017

Issue

Vol. 64 No. 1 (2017)

Section

Inorganic chemistry

License

Except where otherwise noted, articles in this journal are published under the Creative Commons Attribution 4.0 International License