Some Chemistry of Tris(pyrazolyl)methylthiolate Derivatives

Authors

  • Marco Müller FB2, Institute of Inorganic Chemistry, University of Bremen, POBox 330440, 28334 Bremen, Germany
  • Enno Lork FB2, Institute of Inorganic Chemistry, University of Bremen, POBox 330440, 28334 Bremen, Germany
  • Danny Just FB2, Institute of Inorganic Chemistry, University of Bremen, POBox 330440, 28334 Bremen, Germany
  • Rüdiger Mews FB2, Institute of Inorganic Chemistry, University of Bremen, POBox 330440, 28334 Bremen, Germany

Keywords:

scorpionates, tris(azolyl)methylthiolates, chromium complexes, molybdenum complexes, X-ray structures

Abstract

An efficient synthetic method for the preparation of TAS tris(pyrazolyl)methylthiolate (3) is reported. Nucleophilic exchange reactions with 3 gave (pyr)C(=S)SC(pyr)3 (4) and MeSC(pyr)3 (5). 5 acts as scorpionate ligand in [MeSC(pyr)3Cr(CO)3] (6), from the decomposition of TDAE2+ [SC(pyr)3Mo(CO)3–]2 by SO2FCl TDAE2+[O=MoF4-F-Mo(=O)Cl4]2– (8) was isolated. The X-ray structures of 3–6 and 8 are discussed.

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Published

06.11.2013

Issue

Vol. 60 No. 3 (2013)

Section

Inorganic chemistry

License

Except where otherwise noted, articles in this journal are published under the Creative Commons Attribution 4.0 International License