Syntheses, Characterization, Crystal Structures and Antimicrobial Activity of Schiff Base Copper(II) Complexes Derived from 2-Bromo-6-((2-(isopropylamino)ethylimino)methyl)phenol

Authors

  • Yong Yuan ZhouKou Vocational and Technical College
  • Xi-Kun Lu ZhouKou Vocational and Technical College
  • Gao-Qi Zhou Ningbo University
  • Xiao-Yang Qiu Ningbo University

DOI:

https://doi.org/10.17344/acsi.2021.7070

Keywords:

Schiff base, copper complex, crystal structure, antimicrobial activity

Abstract

Three new copper(II) complexes, [Cu(LH)2]Br2 (1), [Cu(LH)2]NCS2 (2), and [Cu(LH)2](NO3)2 (3), where LH is the zwitterionic form of 2-bromo-6-((2-(isopropylamino)ethylimino)methyl)phenol (HL), were synthesized and characterized by elemental analysis, IR and UV-vis spectroscopy. The structures of the complexes were further confirmed by single crystal X-ray structure determination. All compounds are mononuclear copper(II) complexes. The Cu atoms in the complexes are coordinated by two imino N and two phenolate O atoms from two LH ligands, forming square planar coordination. The compounds were assayed for their antimicrobial activities.

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Published

15.12.2021

Issue

Section

Inorganic chemistry