A 3D Coordination Polymer of Sm(III) Using Inorganic Sulphate and Organic Succinate Building Blocks

Authors

  • Subal Chandra Manna Department of Chemistry and Chemical Technology, Vidyasagar University, Midnapore 721102, West Bengal, India
  • Soumen Mistri Department of Chemistry and Chemical Technology, Vidyasagar University, Midnapore 721102, West Bengal, India
  • Ennio Zangrando Dipartimento di Scienze Chimiche e Farmaceutiche, University of Trieste, 34127 Trieste, Italy

Keywords:

Coordination polymer, Hydrothermal synthesis, Samarium(III), Succinate, Sulphate

Abstract

A lanthanide coordination polymeric network, [Sm2(suc)2(SO4)(H2O)2]n (1) (suc = succinate dianion), incorporating both organic succinate and inorganic sulphate building blocks, has been synthesized and characterized by single crystal X-ray diffraction analysis. The complex displays a 3D architecture with two crystallographic independent samarium(III) ions having a distorted capped square antiprismastic geometry with O9 donor set realized by six oxygen atoms from succinate, two from symmetry related sulphate anions and one from an aqua ligand.

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Published

11.10.2013

Issue

Vol. 60 No. 1 (2013)

Section

Inorganic chemistry

License

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