A novel one-pot synthesis of isothiocyanates and cyanamides from dithiocarbamate salts using environmentally benign reagent tetrapropylammonium tribromide

Authors

  • Upasana Bora Sinha Nagaland University Lumami-798627 Nagaland, India
  • Latonglila Jamir Department of environmental sciences, Nagaland University, Lumami-798627, Nagaland, India
  • Neivotsonuo Bernadette Kuotsu Department of Chemistry Kohima Science College (Autonomous) Kohima Nagaland
  • Tovishe Phucho Department of Chemistry, Nagaland University, Lumami-798627, Nagaland, India

DOI:

https://doi.org/10.17344/acsi.2017.3342

Keywords:

TPATB, desulfurization, oxidation, isothiocyanates, sodium bicarbonate, cyanamide

Abstract

A highly efficient and simple protocol for the synthesis of isothiocyanates and cyanamides from their respective amines in the presence of a mild, efficient, and non-toxic reagent tetrapropylammonium tribromide is described. High environmental acceptability of the reagents, cost effectiveness and high yields are the important attributes of this methodology.

Author Biographies

Upasana Bora Sinha, Nagaland University Lumami-798627 Nagaland, India

Associate Professor

Department of Chemistry, Nagaland University, Lumami-798627, Nagaland, India

 

Latonglila Jamir, Department of environmental sciences, Nagaland University, Lumami-798627, Nagaland, India

Assistant Professor

Department of environmental sciences, Nagaland University, Lumami-798627, Nagaland, India

Neivotsonuo Bernadette Kuotsu, Department of Chemistry Kohima Science College (Autonomous) Kohima Nagaland

Assistant Professor

Department of Chemistry
Kohima Science College (Autonomous)
Kohima Nagaland

Tovishe Phucho, Department of Chemistry, Nagaland University, Lumami-798627, Nagaland, India

Assistant Professor

Department of Chemistry, Nagaland University, Lumami-798627, Nagaland, India

Published

12.12.2017

Issue

Section

Organic chemistry