Reductive Heck Reactions and [3+2] Cycloadditions of Unsaturated N,N’-Bistricyclic Imides

Authors

  • Melek Gul University of Amasya, Faculty of Science and Arts, TR-05100, Amasya, Turkey
  • Irem Kulu Yildiz Technical University, Faculty of Science and Arts, Davutpasa Campus, TR-34220 Esenler-Istanbul, Turkey
  • Omer Tahir Gunkara Yildiz Technical University, Faculty of Science and Arts, Davutpasa Campus, TR-34220 Esenler-Istanbul, Turkey
  • Nuket Ocal Yildiz Technical University, Faculty of Science and Arts, Davutpasa Campus, TR-34220 Esenler-Istanbul, Turkey

Keywords:

Alkenes, cycloadditions, heterocycles, hydroarylations, triyclic imides

Abstract

The C-C coupling of N,N'-bis(5-norbornene-2,3-dicarboximide) (3) and N,N'-bis(7-oxa-5-norbornene-2,3-dicarboximide) (6) with aryl and heteroaryl iodides gave under reductive Heck conditions the C-aryl(hetaryl), substituted N,N'-bistricyclic imides 7a-f and 8a,b. The fused spiro-1,3-indandionolylpyrrolidine compounds, 9, 10 and 11 were also obtained from ninhydrine, sarcosine and 3 or 6 via [3+2]cycloaddition.

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Published

22.10.2013

Issue

Vol. 60 No. 1 (2013)

Section

Organic chemistry

License

Except where otherwise noted, articles in this journal are published under the Creative Commons Attribution 4.0 International License